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ISSN: 1023-5086

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ISSN: 1023-5086

Scientific and technical

Opticheskii Zhurnal

A full-text English translation of the journal is published by Optica Publishing Group under the title “Journal of Optical Technology”

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УДК: 535.31, 681, 2.738, 584-14

Birefringence in triphenylamine-containing polyheteroarylene films

For Russian citation (Opticheskii Zhurnal):

Павлов Г.М., Михайлова Н.А., Соловская Н.А., Носова Г.И., Якиманский А.В. Двойное лучепреломление в пленках трифениламинсодержащего полигетероарилена // Оптический журнал. 2014. Т. 81. № 2. С. 67–72.

 

Pavlov G.M., Mikhailova N.A., Solovskaya N.A., Nosova G.I., Yakimanskiy A.V. Birefringence in triphenylamine-containing polyheteroarylene films [in Russian] // Opticheskii Zhurnal. 2014. V. 81. № 2. P. 67–72.

For citation (Journal of Optical Technology):

G. M. Pavlov, N. A. Mikhaĭlova, N. A. Solovskaya, G. I. Nosova, and A. V. Yakimanskiĭ, "Birefringence in triphenylamine-containing polyheteroarylene films," Journal of Optical Technology. 81(2), 104-107 (2014). https://doi.org/10.1364/JOT.81.000104

Abstract:

When a polarized ray is obliquely incident on a film, rotating the film around an axis perpendicular to its surface results in birefringence (BR), which has been studied in a previous paper. Surface BR in triphenylamine-containing polyheteroarylene films has been investigated as a function of the angle of incidence of the light and the film thickness. The results made it possible to estimate the orientational-order parameter of fragments of the macromolecules in the near-surface layers, as well as to estimate the statistical segment length of the polyheteroarylene chains.

Keywords:

films, orientational order, birefringence, polarized light

OCIS codes: 230.0230; 230.3720

References:

1. J. Jiang, Ch. Jiang, W. Yang, H. Zhen, F. Huang, and Y. Cao, “High-efficiency electrophosphorescent fluorene-alt-carbazole copolymers N-grafted with cyclometalated Ir complexes,” Macromolecules 38, 4072 (2005).
2. H. Kruger, A. Wedel, and S. Janietz, “Polymer multilayer systems for electronic applications,” Synth. Met. 127, 267 (2002).
3. G. I. Nosova, A. V. Yakimanskiı˘, N. A. Solovskaya, E. V. Zhukova, R. Yu. Smyslov, A. R. Tameev, E. L. Aleksandrova, and T. V. Magdesieva, “Synthesis and electrooptic properties of triphenylamines and oxadiazole-containing polymers,” Vysokomolek. Soed. B 53, 111 (2011).
4. Y. Q. Tian, C. Y. Chen, M. A. Haller, N. M. Tucker, J. W. Ka, J. D. Luo, S. Huang, and A. K. Y. Jen, “Nanostructured functional block copolymers for electrooptic devices,” Macromolecules 40, 97 (2007).
5. A. P. Kulkarni, Y. Zhu, and S. A. Jenekhe, “Quinoxaline-containing polyfluorenes: synthesis, photophysics, and stable blue electroluminescence,” Macromolecules 38, 1553 (2005).
6. G. I. Nosova, N. A. Solovskaya, K. A. Romashkova, A. V. Yakimanskiı˘, E. L. Aleksandrova, and V. V. Kudryavtsev, “Photosensitivity of polyimides and polyquinazolones based on aromatic and heteroaromatic diamines,” Vysokomolek. Soed. A 50, 1524 (2008).
7. A. N. Cherkasov, M. G. Vitovskaya, and S. V. Bushin, “On the predominant orientation of macromolecules in the surface layers of polymer films,” Vysokomolek. Soed. A 18, 1628 (1976).
8. A. N. Cherkasov and V. A. Pasechnik, Membranes and Sorbents in Biotechnology (Khimiya, Leningrad, 1991).
9. A. E. Grishchenko and A. N. Cherkasov, “Orientational order in polymer surface layers,” Usp. Fiz. Nauk 167, 269 (1997) [Phys.–Usp. 40, 257 (1997)].
10. A. E. Grishchenko, G. M. Pavlov, and G. A. Vikhoreva, “Structure of optically anisotropic surface layers and the distribution of orientational order over the thickness of polymeric films,” Vysokomolek. Soed. B 41, 1347 (1999).
11. G. M. Pavlov and A. E. Grishchenko, “Polysaccharide film technologies: interfacial order and chain rigidity,” Biotechnol. Genet. Eng. Rev. 16, 347 (1999).
12. M. V. Vol’kenshteı˘n, Configuration Statistics of Polymeric Chains (Izd. AN SSSR, Leningrad, 1959).
13. A. E. Grishchenko, Mechanooptics of Polymers (Izd. SPbGU, St. Petersburg, 1996).
14. M. I. Bessonov, “Study of the photoelastic effect in certain polyimides,” Vysokomolek. Soed. A 9, 206 (1967).
15. M. I. Bessonov, M. M. Koton, V. V. Kudryavtsev, and L. A. Laı˘us, Polyimides—A Class of Thermally Stable Polymers (Nauka, Leningrad, 1983).
16. V. N. Tsvetkov, V. V. Korshak, I. N. Shtennikova, Kh. Raubakh, E. S. Krongauz, G. M. Pavlov, G. F. Kolbina, and S. O. Tsepelevich, “Conformation and equilibrium liquid of molecules of polyphenylquinoxalines,” Vysokomolek. Soed. A 21, 83 (1979).
17. G. M. Pavlov, A. N. Kozlov, S. M. Yakopson, S. V. Usova, and Ĺ. S. Efros, “Birefringence and equilibrium stiffness of certain polyamidobenzimidazoles,” Vysokomolek. Soed. A 27, 30 (1985).
18. G. M. Pavlov and A. E. Grishchenko, “Thermodynamic rigidity of chain molecules of polysaccharides and orientational ordering in the surface layers of films of their molecules,” Vysokomolek. Soed. B 47, 1882 (2005).
19. G. M. Pavlov, A. S. Gubarev, I. I. Zaı˘tseva, and Yu. A. Fedotov, “Spontaneous birefringence in the films of certain phenyl-containing polymers,” Vysokomolek. Soed. B 49, 1571 (2007).
20. S. Ya. Magarik, “Macromolecules of polyamic acids and polyimides,” in Polyamic Acids and Polyimides. Synthesis, Transformations, and Structure, M. I. Bessonov and V. A. Zubkov, eds. (CRC Press Inc., Boca Raton, Fla., 1993), pp. 281–362.