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DOI: 10.17586/1023-5086-2018-85-02-03-14
УДК: 548.4, 535.37, 548.23, 548.75, 538.958, 54.05, 54-162, 54-724, 535-15, 538.97, 539.21
Investigation of NV(−) centers and crystallite interfaces in synthetic single-crystal and polycrystalline nanodiamonds by optical fluorescence and microwave spectroscopy
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Publication in Journal of Optical Technology
Осипов В.Ю., Романов Н.М., Богданов К.В., Treussart F., Jentgens C., Rampersaud A. Исследование NV(–) центров и интерфейсов кристаллитов в синтетических моно- и поликристаллических наноалмазах методами оптической флуоресцентной и микроволновой спектроскопии // Оптический журнал. 2018. Т. 85. № 2. С. 3–14. http://doi.org/10.17586/1023-5086-2018-85-02-03-14
Osipov V.Yu., Romanov N.M., Bogdanov K.V., Treussart F., Jentgens C., Rampersaud A. Investigation of NV(−) centers and crystallite interfaces in synthetic single-crystal and polycrystalline nanodiamonds by optical fluorescence and microwave spectroscopy [in Russian] // Opticheskii Zhurnal. 2018. V. 85. № 2. P. 3–14. http://doi.org/10.17586/1023-5086-2018-85-02-03-14
V. Yu. Osipov, N. M. Romanov, K. V. Bogdanov, F. Treussart, C. Jentgens, and A. Rampersaud, "Investigation of NV(−) centers and crystallite interfaces in synthetic single-crystal and polycrystalline nanodiamonds by optical fluorescence and microwave spectroscopy," Journal of Optical Technology. 85(2), 63-72 (2018). https://doi.org/10.1364/JOT.85.000063
Three types of diamond nanoparticles with sizes from 5 to 1000 nm have been investigated, whose crystal lattices include nitrogen-vacancy (NV) centers: detonation nanodiamonds (DNDs), dynamic-synthesis polycrystalline diamonds, and static-synthesis single-crystal diamonds. The electron paramagnetic resonance spectra have been investigated, along with the luminescence and IR absorption spectra of these materials. The DND concentration of NV(−) centers is 2.7 ppm and is highest for particles in the size range up to 7 nm. The concentration of NV(−) centers in polycrystalline diamonds is an order of magnitude less and depends on the average size of the polycrystalline particles, reaching a maximum at 180 nm in the average size range. The luminescence is brightest in 100-nm particles of synthetic Ib diamonds subjected to high-energy-electron irradiation and annealing. The latter with an NV(−) concentration of around 4 ppm can be used as fluorescent markers at the nanolevel.
luminescence, IR spectroscopy, electron paramagnetic resonance, nanodiamond, polycrystallines, shock-wave synthesis, crystallite boundaries, luminescence centers, surface functional groups
Acknowledgements:The research was supported by the Russian Science Foundation (RSF) (project No. 14–13–00795); Japan Society for the Promotion of Science (JSPS) (L17526); Russian Foundation for Basic Research (RFBR) (project No. 17-52-50004 YaF_a).
The authors are grateful to Professor Takuya Hayashi from Shinshu University (Nagano, Japan) for help in obtaining images of particles by high-resolution transmission electron microscopy. V. Yu. Osipov is grateful to Hosei University (Tokyo, Japan) for collaboration.
OCIS codes: 160.4236, 160.2540, 300.6370, 300.6280, 300.6340, 350.3850
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