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DOI: 10.17586/1023-5086-2018-85-05-60-67
УДК: 535.14, 535.34
Nonlinear optical properties of associates of dyes with zinc sulfide nanoparticles
Full text «Opticheskii Zhurnal»
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Publication in Journal of Optical Technology
Ганеев Р.А., Болтаев Г.С., Собиров Б.Р., Усманов Т., Смирнов М.С., Овчинников О.В., Звягин А.И., Волыхин Д.В., Клюев В.Г. Нелинейно-оптические свойства ассоциатов красителей и наночастиц сульфида цинка // Оптический журнал. 2018. Т. 85. № 5. С. 60–67. http://doi.org/10.17586/1023-5086-2018-85-05-60-67
Ganeev R.A., Boltaev G.S., Sobirov B.R., Usmanov T., Smirnov M.S., Ovchinnikov O.V., Zvyagin A.I., Volykhin D.V., Klyuev V.G. Nonlinear optical properties of associates of dyes with zinc sulfide nanoparticles [in Russian] // Opticheskii Zhurnal. 2018. V. 85. № 5. P. 60–67. http://doi.org/10.17586/1023-5086-2018-85-05-60-67
R. A. Ganeev, G. S. Boltaev, B. R. Sobirov, T. Usmanov, M. S. Smirnov, O. V. Ovchinnikov, A. I. Zvyagin, D. V. Volykhin, and V. G. Klyuev, "Nonlinear optical properties of associates of dyes with zinc sulfide nanoparticles," Journal of Optical Technology. 85(5), 302-307 (2018). https://doi.org/10.1364/JOT.85.000302
The Z-scanning method is used to study nonlinear absorption in associates of colloidal zinc sulfide nanoparticles and organic dyes. The nonlinear absorption coefficients of associates of various dyes [thionine, erythrosine, and a pyridine salt of 3,3′-di-(γ-sulfopropyl)-4-4′,5-5′-dibenzo-9-ethylthiacarbocyanine betaine] and ZnS nanoparticles with a mean size of 2 nm are obtained at wavelengths of 1064 and 532 nm of 40-ps pulsed radiation of a YAG:Nd3+ laser. It is presumed that the nonlinear absorption of the ZnS nanoparticles at 1064 nm is caused by three-photon excitation of luminescence centers. The association of the dye molecules with the ZnS nanoparticles reduces the dip in the Z-scanning curves, and this is caused by the acceptor properties of the dyes and probably by the transfer of electron excitations from the luminescence centers of the ZnS nanoparticles to the dye molecules.
colloidal zinc sulfide nanoparticles, dyes, hybrid associates, Z-scanning method, nonlinear light absorption
Acknowledgements:Some of the research results were obtained on the equipment of the Center of Collective Use of Scientific Equipment, Voronezh State University. The studies were carried out with the financial support of the Ministry of Education and Science of the Russian Federation as part of a state contract of the Ministry of Education and Science of the RF in the area of Research Activity in 2017–2019 (Project No. 3.6672.2017/8.9).
OCIS codes: 190.4710, 190.4720
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