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ISSN: 1023-5086

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ISSN: 1023-5086

Scientific and technical

Opticheskii Zhurnal

A full-text English translation of the journal is published by Optica Publishing Group under the title “Journal of Optical Technology”

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DOI: 10.17586/1023-5086-2020-87-09-76-82

УДК: 620.179.118.4

Changes in the surface roughness of optical glasses in a humid environment

For Russian citation (Opticheskii Zhurnal):

Парамонова О.Л., Шардаков Н.Т., Кручинин Д.Ю. Изменение шероховатости поверхности оптических стекол во влажной атмосфере // Оптический журнал. 2020. Т. 87. № 9. С. 76–82. http://doi.org/10.17586/1023-5086-2020-87-09-76-82

 

Paramonova O.L., Shardakov N.T., Kruchinin D.Yu. Changes in the surface roughness of optical glasses in a humid environment // Opticheskii Zhurnal. 2020. V. 87. № 9. P. 76–82. http://doi.org/10.17586/1023-5086-2020-87-09-76-82

For citation (Journal of Optical Technology):

O. L. Paramonova, N. T. Shardakov, and D. Yu. Kruchinin, "Changes in the surface roughness of optical glasses in a humid environment," Journal of Optical Technology. 87(9), 558-561 (2020). https://doi.org/10.1364/JOT.87.000558

Abstract:

Long-term testing of silicate and borate optical glasses is performed in a humid environment. Products of water reacting with glass components are shown to form on the borate glass surface, causing an increase in the roughness parameter Rz. Pretreatment in hexamethyldisiloxane vapors reliably protects glasses from aggressive moisture. Silicate optical glasses are more resistant to humidity and do not require pretreatment. Roughness parameter Rz is found to be an inadequate metric of the roughness of the surface with a protective coating, owing to the limitations of its determination. Topographic measurements are more reliable in this instance.  

Keywords:

optical glass, roughness, wet atmosphere, reaction products, protective film

OCIS codes: 240.5770

References:
1. GOST 13917-92, “Optical materials. Methods of determining chemical resistance. Chemical resistance groups.” 2. GOST 3514-94, “Colorless optical glass. Technical requirements.” 3. GOST 11141-84, “Optical components. Classes of surface cleanness. Control methods.” 4. W. Moro, Microlithography, Part 1 (Mir, Moscow, 1990). 5. GOST 29244-91 (ISO 483-88), “Plastics. Small containers for conditioning and testing using aqueous solutions to maintain constant relative humidity.” 6. OST 3-3312-76, “Scales and grids in products of the optomechanical industry. Principal parameters and labels.” 7. A. A. Bochkarev and V. I. Polyakova, “Sorption hysteresis on microrough surfaces,” Prikl. Mekh. Tekh. Fiz. 53(2), 198–206 (2012). 8. L. I. Demkina, Physical and Chemical Principles of Optical Glass Production (Himiya, Leningrad, 1976). 9. E. V. Baranov and T. I. Shelkovnikova, “Thermodynamic and structural assessment of the transformation of a silicate mesh and glass surface under the action of water and steam,” Vestn. BGTU (7), 37–40 (2016). 10. T. V. Antropova, B. A. Shahmatkin, and I. G. Polyakova, “On the mechanism of extraction of Na2O and B2O3 from the unstable phase of liquated sodium borosilicate glasses into solutions of nitric acid,” Fiz. Khim. Stekla 14(3), 453–461 (1988).