DOI: 10.17586/1023-5086-2024-91-04-26-39
УДК: 535-4;32.517.4; 551.501.816; 551.510.411
High-sensitive laser probing and structural diagnostics of ordered substances, materials, micro- and nanosystems. Review
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Publication in Journal of Optical Technology
Фофанов Я.А., Манойлов В.В. Высокочувствительное лазерное зондирование и структурная диагностика упорядоченных веществ, материалов, микро- и наносистем. Обзор // Оптический журнал. 2024. Т. 91. № 4. С. 26–39. http://doi.org/10.17586/1023-5086-2024-91-04-26-39
Fofanov Ya.A., Manoilov V.V. High-sensitive laser probing and structural diagnostics of ordered substances, materials, micro- and nanosystems. Review [in Russian] // Opticheskii Zhurnal. 2024. V. 91. № 4. P. 26–39. http://doi.org/10.17586/1023-5086-2024-91-04-26-39
Yakov A. Fofanov and Vladimir V. Manoilov, "Highly sensitive laser probing and structural diagnostics of ordered substances, materials, and micro- and nano-systems [Review]," Journal of Optical Technology. 91(4), 228-235 (2024). https://doi.org/10.1364/JOT.91.000228
The subject of study is the laser polarization-optical methods for matter probing. The actuality of this area of research is determined by the need to develop and further improve the methods and means for precision diagnostics of materials. The aim of study is the analysis of the possibilities and prospects for the development of highly sensitive laser polarization-optical and structural diagnostics of ordered substances, functional materials, micro- and nanosystems. Methodology of work. The scanning transmission of the objects under study by polarization-modulated laser radiation is considered. Significant attention is paid to the systematization and generalization of the research results presented in the work. The description of experimental data for actual objects and systems is supplemented by their comparative theoretical analysis. Main results. A hierarchy of criteria for strong and weak polarization responses, which covers a very wide and practically very convenient range of measured birefringence from 1х103 arc. min up to 1х10–4 arc. min, has been studied. It is shown that in this range the analytical scale is linear (proportional), natural noise of laser radiation does not introduce significant obstacles, and the observed polarization-optical responses have the property of additivity, which is useful for their analysis. The effective application of the developed approaches for laser probing and diagnostics of a wide class of objects and media, for example, optical and laser materials and elements with increased optical and structural homogeneity, crystalline magnets, magnetic nanofluids of low concentrations, etc., has been demonstrated. For a magnetic nanofluid based on magnetite in kerosene, polarization responses were registered at a record low minimum volume concentration of 1х10–7. The fundamental possibility of separating and comparatively studying fast random and relatively slow technological variations (increments) of polarization responses of the materials and nanosystems under study has been realized. Practical significance. The results obtained characterize the high sensitivity and quite acceptable information content of the considered methods of matter laser sensing. The approaches being developed can provide a lot of new data about the structural features and associated fluctuations in the parameters of substances and functional materials of wide application. They can be significantly expanded further, for example, to the research and diagnostics of biopolymers, biological fluids, objects of a different nature and composition.
laser probing of matter, hierarchy of polarization responses, optoelectronics, optical materials science, magnetooptics, magnetic nanofluids
Acknowledgements:the work was carried out according to the state assignment of the Ministry of Science and Higher Education of the Russian Federation № 075-01157-23-00 within the framework of the topic FFZM-2022-0008 (state registration number 122032300138-7)
OCIS codes: 300, 200.3050, 260.0260, 250.0250, 120.0120, 230.0230, 230.0250, 210.0210, 140.0140, 260.5430, 120.4290, 160.4236, 210.3820, 280.4788
References:- Azzam R.M.A., Bashara N.M. Ellipsometry and polarized light. Amsterdam, New York: North-Holland Pub. Co., 1977. 529 p.
- Alexandrov A.Ya., Akhmetzyanov M.Kh. Polarizing-optical methods of mechanics of a deformable body. M.: Nauka, 1973. 576 p.
- Alexandrov E.B., Zapassky V.S. Laser magnetic spectroscopy. Leningrad: Nauka. Leningrad branch, 1986. 280 p.
- Schellman J., Jensen H. P. Optical spectroscopy of oriented molecules // Chem. Rev. 1987. V. 87. P. 1359–1399. https://doi.org/10.1021/cr00082a004
- Fofanov Ya.A. Threshold sensitivity in optical measurements with phase modulation // The Report of X Union Symposium and School on High-Resolution Molecular Spectroscopy. Proc. SPIE. 1992. V. 1811. P. 413–414.
- Zapasskii V.S. Polarimetry of regular and stochastic signals in magnetooptics // Physics of the Solid State. 2019. V. 6161. P. 847–852. https://doi.org/10.1134/S106378341905038X
- Yushkin N.P., Volkova N.V., Markova G.A. Optical fluorite. M.: Nauka, 1983. 134 p.
- FofanovYa.A., Afanas’ev I.I., Borozdin S.N. Structural birefringence in crystals of optical fluorite // Journal of Optical Technology. 1998. V. 65. № 9. P. 700–702. elibrary Id 13304602 EDN LFDTQP
- Fofanov Ya.A., Pleshakov I.V., Kuz’min Yu.I. Laser polarization-optical detection of the magnetization process of a magnetically ordered crystal // Journal of Optical Technology. 2013. V. 80. № 1. P. 64–67. https://doi.org/10.1364/JOT.80.000064
- Grishchenko A.E., Cherkasov A.N. Orientational order in polymer surface layers // Phys. Usp. 1997. V. 40. P. 257–272. https://doi.org/10.1070/PU1997v040n03ABEH000210
- Merkulov V.S. Generalized ellipsometry of anisotropic media // Optics and Spectroscopy. 2007. V. 103. Is. 4. P. 629–631. https://doi.org/10.1134/S0030400X07100153
- Acher O., Bigan E., Drevillon B. Improvements of phase-modulated ellipsometry // Rev. Sci. Instrum. 1989. V. 60(1). P. 65–77. https://doi.org/10.1063/1.1140580
- Gupta V.K., Kornfield J.A., Ferencz A., Wegner G. Controlling molecular order in "Hairy-rod" Langmuir-Blodgett films: A polarization-modulation microscopy study // Science. 1994. V. 265(5174). P. 940–942. https://doi.org/10.1126/science.265.5174.940
- Shindo Y., Kani K., Horinaka J., Kuroda R., Harada T. The application of polarization modulation method to investigate the optical homogeneity of polymer films // J. Plast. Film Sheeting. 2001. V. 17(2). P. 164–183.https://doi.org/10.1106/1VGU-5D4Y-2KON-RBQF
- Sokolov I.M., Fofanov Ya.A. Investigations of the small birefringence of transparent objects by strong phase modulation of probing laser radiation // J. Opt. Soc. Am. A.1995. V. 12. № 7. P. 1579–1588. https://doi.org/10.1364/JOSAA.12.001579
- Bitar A., Kaewsaneha C., Eissa M., Jamshaid T., Tangboriboonrat P., Polpanich D., Elaissari A. Ferrofluids: From preparation to biomedical applications // Journal of Colloid Science and Biotechnology. 2014. V. 3. № 1. P. 3–18. https://doi.org/10.1166/jcsb.2014.1080
- Fofanov Ya.A., Bardin B.V. On the polarization responses of the objects with a small optical anisotropy // Nauchnoe Priborostroenie. 2016. V. 26. № 1. P. 58–61. https://doi.org/10.18358/np-26-1-i5861
- Badoz J., Billardon M., Canit J.C., Russel M.F.J. Sensitive devices to determine the state and degree of polarization of a light beam using a birefringence modulator // Journal of Optics. 1977. V. 8. № 6. P. 373–384. https://doi.org/10.1088/0150-536X/8/6/003
- Klyshko D.N., Masalov A.V. Photon noise: observation, squeezing, interpretation // Phys.-Uspekhi. 1995. V. 38(11). P. 1203–1230. https://doi.org/10.1070/PU1995v038n11ABEH000117
- Kuraptsev A.S., Sokolov I.M., Fofanov Ya.A. Coherent specular reflection of resonant light from a dense ensemble of motionless point-like scatters in a slab geometry // Int. J. Mod. Phys. Conf. Ser. 2016. V. 41. P. 1660141. https://doi.org/10.1142/S2010194516601411
- Fofanov Ya., Vetrov V., Ignatenkov B. Laser polarization-optical sounding of optical crystals and ceramics // IEEE Xplore Digital Library. ICLO. 2018. P. 406. https://doi.org/10.1109/LO.2018.8435268
- Diehl R., Jantz W., Nolang B.I., Wettling W. Growth and properties of iron borate FeBO3 // Current Topics in Material Science. V. 11 / Ed. by Kaldis E. Amsterdam: Elsevier Science Publishers B.V., 1984. P. 241–387.
- Kurtzig A.J.J. Faraday rotation in birefringent crystals // Appl. Phys. 1971. V. 42. № 9. P. 3494–3498. https://doi.org/10.1063/1.1660759
- Salanski N.M., Glozman E.A., Seleznev V.N. NMR and the domain structure in FeBO3 single crystal // Sov. Phys. JETP. 1975. V. 41. № 4. P. 704–706.