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ISSN: 1023-5086

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ISSN: 1023-5086

Scientific and technical

Opticheskii Zhurnal

A full-text English translation of the journal is published by Optica Publishing Group under the title “Journal of Optical Technology”

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УДК: 547.97: 535.8, 541.147

The morphology of ZnS nanoparticles in an optical nanocomposite and the effect of adsorbed water on their compatibility with a polymeric matrix

For Russian citation (Opticheskii Zhurnal):

Денисюк И.Ю., Позднякова С.А., Бурункова Ю.Э. Морфология наночастиц ZnS в оптическом нанокомпозите и влияние адсорбированной воды на их совместимость с полимерной матрицей // Оптический журнал. 2014. Т. 81. № 11. С. 103–107.

 

Denisyuk I.Yu., Pozdnyakova S.A., Burunkova Yu.E. The morphology of ZnS nanoparticles in an optical nanocomposite and the effect of adsorbed water on their compatibility with a polymeric matrix [in Russian] // Opticheskii Zhurnal. 2014. V. 81. № 11. P. 103–107.

For citation (Journal of Optical Technology):

I. Yu. Denisyuk, S. A. Pozdnyakova, and Yu. É. Burunkova, "The morphology of ZnS nanoparticles in an optical nanocomposite and the effect of adsorbed water on their compatibility with a polymeric matrix," Journal of Optical Technology. 81(11), 697-700 (2014). https://doi.org/10.1364/JOT.81.000697

Abstract:

This paper discusses methods of obtaining ZnS nanoparticles with various concentrations of water molecules on the surface. To do this, they are synthesized in different media: in an aqueous medium, a nonaqueous medium, and with delayed introduction of water. It is found that, in the absence of water, a transparent glassy material composed of self-organized close-packed nanoparticles is formed on the surface of the ZnS nanoparticle (nonaqueous synthesis) after the solvent is removed. The methods of derivatography and IR spectroscopy are used to investigate the surface structure of ZnS nanoparticles stabilized by shells composed of an organic acid. It is shown by IR spectroscopy that chemical bonds are formed between the surface of the nanoparticles and the carboxyl group of the monomer.

Keywords:

nanoparticles, adsorption, nanocomposite, self-organization

OCIS codes: 310.6870, 160.5470, 240.0310

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