Estimating the relaxation times of “lattice” translational quasi-particle excitations in liquid systems on the basis of long-wavelength IR spectra in the cluster–continuum approximation

Демидов В.Н. Оценка времен релаксации "решеточных" трансляционных квазичастичных возбуждений в жидких системах на основе длинноволновых ИК спектров в рамках кластерно-континуального приближения // Оптический журнал. 2008. Т. 75. № 4. С. 3–11.

Demidov V.N. Estimating the relaxation times of “lattice” translational quasi-particle excitations in liquid systems on the basis of long-wavelength IR spectra in the cluster–continuum approximation [in Russian] // Opticheskii Zhurnal. 2008. V. 75. № 4. P. 3–11.

V. N. Demidov, "Estimating the relaxation times of “lattice” translational quasi-particle excitations in liquid systems on the basis of long-wavelength IR spectra in the cluster–continuum approximation," Journal of Optical Technology. 75 (4), 211-217 (2008). https://doi.org/10.1364/JOT.75.000211

Quasi-lattice translational vibrational transitions in liquid systems, accompanied by energy absorption in the low-frequency IR spectral region, and the relaxation of excited vibrational states are interpreted in terms of the theory of autovibrational processes. By using a one-dimensional iterated mapping of a sequence in the form of recursion relations of the theory of autovibrations, a relationship is found between the relaxation times of phononlike “lattice” translational quasi-particle vibrational excitations in liquid systems and the corresponding vibrational frequencies, and the relaxation times are also estimated for a number of nonpolar, polar, and associated molecular liquids. The problem of the applicability of the quantum-mechanical indeterminacy relation for energy and time in low-frequency IR spectroscopy is discussed.