ru
Back
DOI: 10.17586/1023-5086-2026-93-12-27-37
УДК: 620.193.73
Effect of chemical composition on pitting corrosion resistance of AISI 304 stainless steel after laser surface structuring
Суслов Р.Р., Филатов И.А., Москвин М.К., Бухаров М.С., Давыдова Е.А., Михалевич М.А., Гришина А.И., Воркель В.А., Романова Г.В. Влияние химического состава нержавеющей стали AISI 304 после лазерного воздействия на стойкость к питтинговой коррозии // Оптический журнал. 2026. Т. 93. № 12. С. 27–37. http://doi.org/10.17586/1023 5086-2026-93-12-27-37
Suslov R.R., Filatov I.A., Moskvin M.K., Bukharov M.S., Davydova E.A., Mikhalevich M.A., Grishina A.I., Vorkel V.A., Romanova G.V. Effect of chemical composition on pit ting corrosion resistance of AISI 304 stainless steel after laser surface structuring [in Russian] // Opticheskii Zhurnal. 2026. V. 93. № 12. P. 27–37. http://doi.org/10.17586/1023-5086-2026-93- 12-27-37
Subject of study. Chemical composition and resistance to pitting corrosion of AISI 304 stainless steel after laser structuring. Aim of the study. Establishing the possibility of increasing the resistance of AISI 304 steel to pitting corrosion by changing the chemical composition of the surface layers during laser structuring. Method. Laser structuring of the surface using parameters that ensure heating and melting of the material. The study included an analysis of the surface morphology using microscopy and profilometry, a study of the phase-chemical composition of the surface, and electrochemical corrosion tests. Main results. Laser structuring is shown to cause a redistribution of chemical elements in the near-surface layer and the formation of an oxide film. It is found that an increase in the content of manganese oxide and iron reduces the resistance to pitting corrosion, while the presence of nickel and its oxide contributes to an increase in the protective properties. Laser structuring modes that provide increased corrosion resistance of steel are identified. The scientific novelty lies in establishing a correlation between the chemical composition of a laser-modified surface layer and the steel’s resistance to pitting corrosion. Practical significance. The obtained results confirm the feasibility of using laser structuring as a localized and contactless method for passivating steel components without the use of consumables. This method holds promise for extending the service life and protecting small components of sensors and other devices operating in aggressive environments.
laser processing, pitting corrosion, oxide layer, stainless steel, chemical composition, passivation
Acknowledgements:the study was financially supported by the Russian Science Foundation, Project № 24-79-00255 "Method of laser structuring of metals to prevent biofouling and mineral sediments of calcium and magnesium salts". This work was supported by the Ministry of Science and Higher Edu cation of the Russian Federation, Project № 125012200581-1 "Development of the physicochemical fundamentals of corrosion processes in metals and alloys and methods for their protection".
OCIS codes: 160.3900, 350.3850
References:1. Wang Z., Dirrenberger J., Lapouge P., Dubent S. Laser treatment of 430 ferritic stainless steel for enhanced mechanical properties // Materials Science and En gineering: A. 2022. V. 831. P. 142205. DOI:10.1016/j. msea.2021.142205
2. Liu W., Pan H., Wang Q. et al. Microstructures and corrosion behaviors of nickel-based coating prepared by laser cladding and electroplated hard chromium coating // Engineering Failure Analysis. 2022. V. 140. P. 106612. DOI:10.1016/j.engfailanal.2022.106612
3. Wang A., Feng A., Chen Y. et al. Study on the corrosion resistance of 316L stainless steel by picosecond laser cleaning // Journal of Solid State Electrochemistry. 2024. P. 2495–2504. DOI:10.1007/s10008-023-05782-6
4. Пронин С.П., Умбетов С.В. Исследование возможности оценки глубины проникновения коррозии в металл по изображению корродированной поверхности // Оптический журнал. 2022. Т. 89. № 1. С. 63–73. DOI:10.17586/1023-5086-2022-89-01-63-73
Pronin S.P., Umbetov S.V. Can the corrosion-penetra tion depth into a metal be estimated from an image of the corroded surface? // Journal of Optical Technology. 2022. V. 89. № 1. P. 44–51. DOI:10.1364/JOT.89. 000044
5. Guo L., Huang H., Jia C., Romanov K. Axial behavior of square CFST with local corrosion simulated by artificial notch // Journal of Constructional Steel Research. 2020. V. 174. P. 106314. DOI:10.1016/j. jcsr.2020.106314
6. Farh H.M.H., Seghier M.E.A.B., Zayed T. A comprehensive review of corrosion protection and control techniques for metallic pipelines // Engineering Failure Analysis. 2023. V. 143. P. 106885. DOI:10.1016/ j.engfailanal.2022.106885
7. Akpan E.D., Singh A.K., Lgaz H. et al. Coordination compounds as corrosion inhibitors of metals: A review // Coordination Chemistry Reviews. 2024. V. 499. P. 215503. DOI:10.1016/j.ccr.2023.215503
8. Yoo Y.-R., Choi S.-H., Kim Y.-S. Effect of laser peening on the corrosion properties of 304L stainless steel // Materials. 2023. V. 16. Art. 804. DOI:10.3390/ ma16020804
9. Guan L., Ye Z., Zhong J., Li Y., Zhang Y. Enhance ment of corrosion resistance of 304L stainless steel treated by massive laser shock peening // Optics & La ser Technology. 2022. V. 154. P. 108319. DOI:10.1016/ j.optlastec.2022.108319
10. Suslov R., Prokopiev V., Filatov I. et al. Effect of chemical composition on pitting corrosion resistance of AISI 430 stainless steel after laser surface structuring // Optics & Laser Technology. 2025. V. 183. P. 112286. DOI:10.1016/j.optlastec.2024.112286
11. Марочник сталей и сплавов. 4-е изд., переработ. и доп. / Ю.Г. Драгунов, А.С. Зубченко, Ю.В. Каширский и др. Под общей ред. Ю.Г. Драгунова и А.С. Зубченко. М.: Машиностроение, 2014. 1216 с.
Steel and alloy brand book. 4th edition, revised and enlarged / Dragunov Yu.G., Zubchenko A.S., Kashirsky Yu.V. et al. Edited by Dragunov Yu.G., Zubchenko A.S. Moscow: Mashinostroenie, 2014. 1216 p.
12. ГОСТ 5632-2014. Легированные нержавеющие стали и сплавы коррозионно-стойкие, жаростойкие и жаропрочные. Марки. Введ. 01.01.15. М.: Стандартинформ, 2015. 112 с.
GOST (Russian National Standard) 5632-2014. Corrosion-resistant, heat-resistant and heat-proof alloy stainless steels and alloys. Grades [in Russian]. Introd. 01.01.15. Moscow: Standartinform, 2015. 112 p.
13. Chu T.K., Ho C.Y. Thermal conductivity and electrical resistivity of eight selected AISI stainless steels // Thermal conductivity 15. Boston, MA: Springer US, 1978. P. 79–104. DOI:10.1007/978-1-4615-9083-5_12
14. Либенсон М.Н. Лазерно-индуцированные оптические и термические процессы в конденсированных средах. СПб: Наука, 2007. 423 с.
Libenson M.N. Laser-induced optical and thermal processes in condensed matter. St. Petersburg: Nauka, 2007. 423 p.
15. Donik Č., Kocijan A., Grant J.T. et al. XPS study of duplex stainless steel oxidized by oxygen atoms // Corrosion Science. 2009. V. 51. № 4. P. 827–832. DOI:10.1016/j.corsci.2009.01.021
16. Marasco A.L., Young D.J. The oxidation of Iron Chromium-Manganese alloys at 900 C // Oxidation of Metals. 1991. V. 36. № 1. P. 157–174. DOI:10.1007/ BF00938460
17. Khollari M.A.R., Deen K.M., Asselin E. A mechanistic study of iron passivation and transpassive behavior in sulfate solutions using thermo-kinetic diagrams // Mate rials Degradation. 2025. V. 9. № 1. P. 119. DOI:10.1038/ s41529-025-00667-7
18. Kwon H., Park K. Effects of manganese on the passivity of Fe-18Cr-xMn (x = 0, 6, 12) // ECS Transactions. 2006. V. 1. № 4. P. 313. DOI:10.1149/1.2215515
19. Pardo A., Merino M.C., Coy A.E. et al. Pitting corrosion behaviour of austenitic stainless steels –combining effects of Mn and Mo additions // Corrosion Science. 2008. V. 50. № 6. P. 1796–1806. DOI:10.1016/ j.corsci.2008.04.005
20. Potgieter J.H., Olubambi P.A., Cornish L. et al. Influence of nickel additions on the corrosion behaviour of low nitrogen 22% Cr series duplex stainless steels // Corrosion Science. 2008. V. 50. № 9. P. 2572–2579. DOI:10.1016/j.corsci.2008.05.023